fbpx

一品探花论坛

CHASE Solar Hub pioneers liquid fuel conversion

At the center's Chapel Hill headquarters, more than 100 researchers work to turn sunlight into methanol.

Hueynwoo Yang wearing grey sweatshirt and filling liquid vials with machinery.
Hyuenwoo Yang, a postdoctoral researcher, works in the lab at Murray Hall. The mission of CHASE Solar Hub is to develop liquid fuels from light-absorbing semiconductor materials. (Johnny Andrews/UNC-Chapel Hill)

The sun powers our solar system, lights our Earth and helps sustain life as we know it, yet much of the sun鈥檚 energy remains untapped by humans. As the world grapples with emerging climate and energy crises, scientists are increasingly looking toward the sun for solutions.

一品探花论坛 researchers have taken on a prominent role in the development of that science, especially since the 2020 launch of the Center for Hybrid Approaches in Solar Energy to Liquid Fuels in Chapel Hill.

The CHASE Solar Hub, funded by a five-year, $40-million grant from the U.S. Department of Energy Office of Basic Energy Sciences, positions UNC-Chapel Hill as a national leader in solar energy research. Now in Year 4, CHASE has already made significant headway, including the development of three mechanisms that convert sunlight, water and carbon dioxide into liquid methanol.

Man in lab coat in background with dry erase board filled with equations in foreground.

Stephen Tereniak, a synthesis scientist in the CHASE Solar Fuels Hub, works in the lab on March 22, 2024, in Murray Hall on the campus of the University of North 一品探花论坛 at Chapel Hill. The mission of CHASE (Center for Hybrid Approaches in Solar Energy to Liquid Fuels) is to develop liquid fuels from light-absorbing semiconductor materials. (Johnny Andrews/UNC-Chapel Hill)

鈥淭he big-picture goal of CHASE is to make meaningful progress in the science behind using sunlight to drive the conversion of energy-poor molecules 鈥 like carbon dioxide and water 鈥 into energy-rich fuel,鈥 said Jillian Dempsey, CHASE deputy director and Bowman and Gordon Gray Distinguished Term Professor of chemistry.

鈥淭here鈥檚 obviously a major need to move away from fossil fuel energy sources toward sustainable energy sources to meet our growing energy needs and mitigate climate change.鈥

Despite the proliferation of solar panels and other photovoltaic devices, the conversion of sunlight into liquid fuel is a relatively undeveloped science. Because our energy economy runs on liquid fuel 鈥 and because liquid fuel has a much higher energy density than batteries 鈥 its production from sunlight could have massive global ramifications.

一品探花论坛 is working in partnership with six institutions 鈥 Yale, Princeton, Emory and NC State universities, the University of Pennsylvania, and Brookhaven National Laboratory 鈥 to create a highly collaborative environment to solve a complex and multifaceted issue.

鈥淲e are not a single researcher working on this problem,鈥 Dempsey said. 鈥淲e are a hub of over 100 people from distinct backgrounds, distinct expertise and complementary expertise working on this problem.鈥

What makes liquid fuel production from sunlight so challenging?

Picture the gasoline in your car. When gasoline combusts, it produces carbon dioxide, water vapor and energy. What CHASE is trying to do, in essence, is to reverse that reaction and use carbon dioxide, water and energy to produce fuel.

This 鈥渦phill鈥 chemical reaction does not occur spontaneously and requires energy. By pairing light-absorbing semiconductors with molecular catalysts, CHASE aims to harness that energy from the sun to make liquid fuels.

Liquid being experimented on in vials.

Hyuenwoo Yang, a postdoctoral researcher in the lab of Greg Parsons at North 一品探花论坛 State University, works in the lab on March 22, 2024, in Murray Hall on the campus of the University of North 一品探花论坛 at Chapel Hill. The mission of CHASE (Center for Hybrid Approaches in Solar Energy to Liquid Fuels) is to develop liquid fuels from light-absorbing semiconductor materials. North 一品探花论坛 State University is among a number of universities who have partnered with UNC in this research venture. (Johnny Andrews/UNC-Chapel Hill)

CHASE is focused on developing the science that could lay the foundations for future technology.

鈥淥ne can imagine in the future having a closed-loop system, where you take a carbon-containing liquid fuel and burn it very much in the way we do now, but do it in a controlled way, in what鈥檚 called a fuel cell,鈥 said Gerald Meyer, CHASE director and chemistry professor. 鈥淵ou could burn the liquid fuel, get the carbon dioxide and then recycle it without releasing it to the atmosphere.鈥

Such a system would create a more sustainable and renewable energy source while also mitigating the climate impact of carbon dioxide in the atmosphere. But there are still questions to answer and problems to solve before that kind of technology is available. With CHASE鈥檚 funding set to expire in 2025, both Meyer and Dempsey said the hope is for a grant renewal.

鈥淲e鈥檙e in Year 4, and we鈥檙e hopeful that we鈥檒l be able to renew CHASE for another five years,鈥 Dempsey said. 鈥淲e want to push the science forward even further and bring it to that technology-readiness level.鈥

This research was supported as part of CHASE, an Energy Innovation Hub funded by the U.S. Department of Energy, Office of Science.